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Characterization and reactivity of copper(II) and copper(III) -aryl intermediates in aminoquinoline-directed C-H functionalization

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Our study has important implications for our understanding of enzymatically active and inactive glutaredoxins and could be useful for the design and optimization of artificial glutaredoxins, glutaredoxin-coupled fluorescent redox sensors and transition-state inhibitors

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The nanocarrier amount was normalized to the protein concentration in the samples measured by BCA protein assay (Thermo Fischer Scientific)